Synthesis of a sucrose-based macrocycle with unsymmetrical monosaccharides "arms"
نویسندگان
چکیده
An efficient methodology for the selective substitution of both terminal positions (C6 and C6') in 1',2,3,3',4,4'-hexa-O-benzylsucrose with different unsaturated monosaccharide units is presented. Such a highly functionalized intermediate was cyclized under RCM conditions to afford a macrocyclic derivative containing a 31-membered ring in 26% yield.
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عنوان ژورنال:
دوره 14 شماره
صفحات -
تاریخ انتشار 2018